城市污水主要有工業(yè)污水和生活污水兩大類。城市污水中含有大量顆粒狀和塊狀懸浮物，懸浮物分散的均勻性很大，濁度大，企業(yè)排放的污水，存在色度，濁度，油類物質(zhì)，氧化劑、還原劑或強(qiáng)酸、強(qiáng)堿等干擾，對其PH值的測定通常選用玻璃電極法，可以排除色度、濁度，油類物質(zhì)，氧化劑、還原劑等因素的干擾，但對于強(qiáng)堿類廢水，尤其是PH值在l0以上時，將產(chǎn)生“鈉差”，讀數(shù)偏低，應(yīng)選用特制的“低鈉差”玻璃電極。
城市污水PH值變化范圍較大，受溫度影響也較大，為此可選帶有溫度自動補(bǔ)償?shù)膬x器，以降低溫度變化產(chǎn)生的誤差。同時，選用與PH計配套或品牌型號一致的玻璃電極也可降低測量誤差，在測量城市污水之前，應(yīng)先用與水樣PH值相近的標(biāo)準(zhǔn)緩沖溶液對儀器進(jìn)行校正，以減少測量誤差，同時可以降低強(qiáng)堿產(chǎn)生的“鈉差”，提高測量精度。測量城市污水PH值，玻璃電極容易受有機(jī)物質(zhì)尤其是油類的污染，此時先用稀鹽酸清洗，溶液無機(jī)鹽后用純凈水清洗干凈，但不能用無水酒精清洗，否則會使電極性能變劣，電極清洗干凈后在水中浸泡一晝夜，在電極膜表面形成水化層后再使用。
六、PH電極的使用壽命
PH電極的使用壽命取決于使用條件與使用方法是否正確。
1、測量介質(zhì)。包括清潔溶液、粘稠液、懸濁液、強(qiáng)酸、強(qiáng)堿和非水溶液。其中有些對PH電極的膜有強(qiáng)的腐蝕性。如強(qiáng)酸、強(qiáng)堿溶液，特別是強(qiáng)堿溶液，有些會黏附在電極上，如粘稠液等。電極在這種介質(zhì)中使用壽命比在清潔溶液中的使用壽命短。
2、使用溫度。電極的使用溫度應(yīng)該選擇在正常的使用溫度范圍內(nèi)，如果經(jīng)常在溫度范圍的上限使用，電極的使用壽命會縮短，會嚴(yán)重?fù)p壞電極，溫度愈高，損壞程度愈大。
3、清洗與保存。電極使用完畢后，要注意膜的清洗，對復(fù)合電極來說，更要注意液接界部位的清洗，清洗完畢后，將電極膜部位儲存于規(guī)定的電極保護(hù)溶液中。
分析人員在使用PH電極的過程中，要經(jīng)常總結(jié)經(jīng)驗教訓(xùn)，規(guī)范操作，加強(qiáng)儀器的維護(hù)，才能及時提供準(zhǔn)確可靠的分析結(jié)果。
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6GK5602-0BA00-2AA3 SCALANCE S602
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6GK5613-0BA00-2AA3 SCALANCE S613
6GK5623-0BA10-2AA3 SCALANCE S623
6GK5627-2BA10-2AA3 SCALANCE S627-2M
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6GK1700-0AA08-3AA0 SOFTWARE CD PC/WINDOWS EDITION 2008
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6GK1700-0AA11-3AA0 SOFTWARE DVD PC/WINDOWS V8.1
6GK1700-0AA12-0AA0 SOFTWARE DVD PC/WINDOWS V12
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6GK1704-1CE20-3AA0 SOFTNET-S7 VERSION 2.0 UPGRADE UNIX X86
6GK1704-1CF02-3AA0 SOFTNET-S7/SPARC V1.2
6GK1704-1CF02-3AA4 SOFTNET-S7 VERSION 1.2 UPGRADE SPARC
6GK1704-1CF20-3AA0 SOFTNET-S7 VERSION 2.0 UPGRADE SPARC
6GK1704-1CG02-3AA0 SOFTNET-S7/ UNIX HP-UX
6GK1704-1CG02-3AA4 SOFTNET-S7 VERSION 1.2 UPGRADE HP
6GK1704-1CG20-3AA0 SOFTNET-S7 VERSION 2.0 HP UPGRADE
6GK1704-1CU02-3AA4 SOFTNET-S7 VERSION 1.2 UPGRADE SCO
6GK1704-1CU20-3AA4 SOFTNET-S7 VERSION 2.0 UPGRADE UNIX
6GK1704-1CW00-3AE0 IE SOFTNET-S7 UPGRADE FROM EDITION 2006
6GK1704-1CW00-3AE1 IE SOFTNET-S7 UPGRADE FOR EDITION 2005
6GK1704-1CW00-3AL0 IE SOFTNET-S7 SW UPDATE SERVICE
6GK1704-1CW00-3AN0 IE SOFTNET-S7 2006
6GK1704-1CW00-3AP8 IE SOFTNET-S7 EPL-MASTER
6GK1704-1CW00-3AQ0 IE SOFTNET-S7 EPL-ROYALTY
6GK1704-1CW00-3AR8 IE SOFTNET-S7 EPL-MAINTENANCE
6GK1704-1CW00-3MA0 IE SOFTNET-S7 2005+HF1
6GK1704-1CW08-1AA0 IE SOFTNET-S7 V8.0
6GK1704-1CW08-2AA0 SOFTNET-IE S7 V8.2
6GK1704-1CW12-0AA0 SOFTNET-IE S7 V12
6GK1704-1CW12-0AK0 SOFTNET-IE S7 V12 DL
6GK1704-1CW33-3AA0 IE SOFTNET-S7 Basic/Win98, 2000
6GK1704-1CW60-3AA0 IE SOFTNET-S7 Windows V6.0
6GK1704-1CW61-3AA0 IE SOFTNET-S7 V6.0
6GK1704-1CW62-3AP8 IE SOFTNET-S7 V6.2 EPL-MASTER
6GK1704-1CW62-3AQ0 IE SOFTNET-S7 V6.2 EPL-ROYALTY
6GK1704-1CW63-3AA0 IE SOFTNET-S7 2005
6GK1704-1CW63-3AB0 IE SOFTNET-S7 2005
6GK1704-1CW63-3AP8 IE SOFTNET-S7 2005 + HF1 EPL-MASTER
6GK1704-1CW63-3AQ0 IE SOFTNET-S7 2005 + HF1 EPL-ROYALTY
6GK1704-1CW64-3AA0 IE SOFTNET-S7 2006
6GK1704-1CW64-3AE0 IE SOFTNET-S7 2006 UPGRADE V6.0 A.HIGHER
6GK1704-1CW70-3AA0 IE SOFTNET-S7 2007
6GK1704-1CW70-3AK0 IE SOFTNET-S7 2007 LICENSE KEY
6GK1704-1CW71-3AA0 IE SOFTNET-S7 2008
6GK1704-1CW71-3AK0 IE SOFTNET-S7 2008
6GK1704-1CW80-3AA0 IE SOFTNET-S7 V8.0
6GK1704-1HW00-3AE0 IE SOFTN.PN IO UPGRADE F. EDITION 2006
6GK1704-1HW00-3AE1 IE SOFTNET PN IO UPGRADE FOR 2006
6GK1704-1HW00-3AL0 IE SOFTNET PN IO SW UPDATE SERVICE
6GK1704-1HW00-3AN0 IE SOFTNET PN IO 2006
6GK1704-1HW00-3MA0 IE SOFTNET PN IO 2005+HF1
6GK1704-1HW08-1AA0 IE SOFTNET PN IO V8.0
6GK1704-1HW08-2AA0 SOFTNET-IE PN IO V8.2
6GK1704-1HW12-0AA0 SOFTNET-IE PN IO V12
6GK1704-1HW62-3AA0 SIMATIC NET, IE SOFTNET PN IO/
6GK1704-1HW63-3AA0 IE SOFTNET PN IO 2005
6GK1704-1HW63-3AB0 IE SOFTNET PN IO 2005
6GK1704-1HW64-3AA0 IE SOFTNET PN IO 2006
6GK1704-1LW12-0AK0 SOFTNET-IE S7 LEAN V12 DL
6GK1704-1LW61-3AA0 SIMATIC NET IE SOFTNET-S7 LEAN/
6GK1704-1LW63-3AA0 IE SOFTNET-S7 LEAN 2005
6GK1704-1LW63-3AB0 IE SOFTNET-S7 LEAN 2005
6GK1704-1LW64-3AA0 IE SOFTNET-S7 LEAN 2006
6GK1704-1LW64-3AE0 IE SOFTNET-S7 LEAN UPGRADE EDITION 2006
6GK1706-0XW00-3AE0 IE DX OPC-SERVER UPGRADE EDITION 2006
6GK1706-0XW00-3AE1 IE DX OPC-SERVER UPGRADE EDITION 2005
6GK1706-0XW00-3AL0 IE DX OPC-SERVER SW UPDATE SERVICE
6GK1706-0XW63-3AA0 IE DX OPC-SERVER 2005
6GK1706-0XW63-3AB0 IE DX OPC-SERVER 2005
6GK1706-0XW64-3AA0 IE DX OPC-SERVER 2006
6GK1706-0XW64-3AE0 IE DX OPC-SERVER UPGRADE 2006
6GK1706-0XW70-3AA0 IE DX OPC-SERVER 2007
6GK1706-0XW70-3AK0 IE DX OPC-SERVER 2006
6GK1706-1CW08-1AA0 IE S7 OPC REDUNDANCY
6GK1706-1CW08-2AA0 IE S7 OPC REDUNDANCY V8.2
6GK1706-1CW12-0AA0 IE S7 OPC REDUNDANCY V12
6GK1706-1NW00-3AE0 IE SNMP OPC-SERVER BASIC UPGRADE 2006
6GK1706-1NW00-3AE1 IE SNMP OPC-SERVER BASIC UPGRADE 2005
6GK1706-1NW00-3AL0 IE SNMP OPC-SERVER BASIC SW UPDATE SERV
6GK1706-1NW08-1AA0 IE SNMP OPC-SERVER BASIC V8.0
6GK1706-1NW08-2AA0 IE SNMP OPC-SERVER BASIC V8.2
6GK1706-1NW08-2AC0 IE SNMP OPC-SERVER POWERPACK V8.2
6GK1706-1NW12-0AA0 IE SNMP OPC-SERVER BASIC V12
6GK1706-1NW12-0AC0 IE SNMP OPC-SERVER POWERPACK V12
6GK1706-1NW61-3AA0 IE SNMP OPC-SERVER V6.0
6GK1706-1NW61-3AA4 IE SNMP OPC-SERVER V6.0 POWERPACK
6GK1706-1NW63-3AA0 IE SNMP OPC-SERVER BASIC 2005
6GK1706-1NW63-3AA4 IE SNMP OPC-SERVER POWERPACK 2005 UPGR
6GK1706-1NW63-3AB0 IE SNMP OPC-SERVER BASIC 2005
6GK1706-1NW63-3AD0 IE SNMP OPC-SERVER POWERPACK 2005
6GK1706-1NW64-3AA0 IE SNMP OPC-SERVER BASIC 2006
6GK1706-1NW64-3AC0 IE SNMP OPC-SERVER POWERPACK 2006 UPGR
6GK1706-1NW64-3AE0 IE SNMP OPC-SERVER BASIC 2006 UPGRADE
6GK1706-1NW70-3AA0 IE SNMP OPC-SERVER BASIC 2007
6GK1706-1NW70-3AC0 IE SNMP OPC-SERVER POWERPACK 2007
6GK1706-1NW70-3AK0 IE SNMP OPC-SERVER BASIC 2007
6GK1706-1NW70-3AK4 IE SNMP OPC-SERVER POWERPACK 2007
6GK1706-1NW71-3AA0 IE SNMP OPC-SERVER BASIC 2008
6GK1706-1NW80-3AA0 IE SNMP OPC-SERVER BASIC V8.0
6GK1706-1NX00-3AE0 IE SNMP OPC-SERVER EXTENDED UPGRADE 2006
6GK1706-1NX00-3AE1 IE SNMP OPC-SERVER EXTENDED UPGRADE 2005
6GK1706-1NX00-3AL0 IE SNMP OPC-SERVER SW UPDATE SERVICE
6GK1706-1NX08-1AA0 IE SNMP OPC-SERVER EXTENDED V8.0
6GK1706-1NX08-2AA0 IE SNMP OPC-SERVER EXTENDED V8.2
6GK1706-1NX12-0AA0 IE SNMP OPC-SERVER EXTENDED V12
6GK1706-1NX61-3AA0 IE SNMP OPC-SERVER EXTENDED V6.0
6GK1706-1NX63-3AA0 IE SNMP OPC-SERVER EXTENDED 2005
6GK1706-1NX63-3AB0 IE SNMP OPC-SERVER EXTENDED 2005
6GK1706-1NX64-3AA0 IE SNMP OPC-SERVER EXTENDED 2006
6GK1706-1NX64-3AE0 SNMP OPC-SERVER EXTENDED UPGRADE 2006
6GK1706-1NX70-3AA0 IE SNMP OPC-SERVER EXTENDED 2007
6GK1706-1NX70-3AK0 IE SNMP OPC-SERVER EXTENDED 2007
6GK1706-1NX71-3AA0 IE SNMP OPC-SERVER EXTENDED 2008
6GK1706-1NX71-3AC0 IE SNMP OPC-SERVER POWERPACK 2008
6GK1706-1NX80-3AA0 IE SNMP OPC-SERVER EXTENDED V8.0
6GK1706-1NX80-3AC0 IE SNMP OPC-SERVER POWERPACK V8.0
6GK1706-5CW12-0AA0 PB S7 OPC REDUNDANCY V12
6GK1711-1EW00-3AE0 IE SOFTNET-S7 RNA UPGRADE EDITION 2006
6GK1711-1EW00-3AL0 IE SOFTNET RNA SW UPDATE SERVICE
6GK1711-1EW08-1AA0 IE SOFTNET RNA
6GK1711-1EW08-2AA0 SOFTNET-IE RNA V8.2
6GK1711-1EW12-0AA0 SOFTNET-IE RNA V12
6GK1716-0HB00-3AE0 S7-REDCONNECT UPGRADE EDITION 2006
6GK1716-0HB00-3AE1 S7-REDCONNECT UPGRADE EDITION 2005
6GK1716-0HB00-3AL0 S7-REDCONNECT SW UPDATE SERVICE
6GK1716-0HB00-3AN0 S7-REDCONNECT 2006
6GK1716-0HB00-3MA0 S7-REDCONNECT 2003
6GK1716-0HB08-1AA0 HARDNET-IE S7 REDCONNECT V8.1
6GK1716-0HB08-1AC0 S7-REDCONNECT V8.0 POWERPACK
6GK1716-0HB08-2AA0 HARDNET-IE S7 REDCONNECT V8.2
6GK1716-0HB08-2AC0 HARDNET-IE S7 REDCONNECT V8.2
6GK1716-0HB12-0AA0 HARDNET-IE S7 REDCONNECT V12
6GK1716-0HB12-0AC0 HARDNET-IE S7 REDCONNECT PP V12
6GK1716-0HB12-0AK0 HARDNET-IE S7 REDCONNECT V12 DL
6GK1716-0HB12-0AK1 HARDNET-IE S7 POW.P. RED V12 DL
6GK1716-0HB14-3AA0 S7-REDCONNECT V1.4
6GK1716-0HB14-3AA4 S7-REDCONNECT V1.4 UPGRADE
6GK1716-0HB60-3AA0 S7-REDCONNECT V 6.0
6GK1716-0HB60-3AA4 S7-REDCONNECT V 6.0 Upgrade
6GK1716-0HB61-3AA0 S7-REDCONNECT V6.0
6GK1716-0HB61-3AA4 S7-REDCONNECT V6.0 UPGRADE
6GK1716-0HB63-3AA0 S7-REDCONNECT 2005
6GK1716-1CB00-3MA0 IE S7-1613 LICENSE PACK
6GK1716-1CB08-1AA0 IE S7-1613 EDITION V8.0
6GK1716-1CB08-2AA0 HARDNET-IE S7 V8.2
6GK1716-1CB12-0AA0 HARDNET-IE S7 V12
6GK1716-1CB12-0AK0 HARDNET-IE S7 V12 DL
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